METHYL PIVALATE

PRODUCT IDENTIFICATION

CAS NO. 598-98-1

METHYL PIVALATE

EINECS NO. 209-959-1
FORMULA (CH3)3CCOOCH3
MOL WT. 116.16

H.S. CODE

2915.60

TOXICITY

 
SYNONYMS 2,2-Dimethyl-propanoic acid, methyl ester;
Methyl trimethylacetate; Propanoic acid, 2,2-dimethyl-, methyl ester; Methyl 2,2-dimethylpropionate; Neopentanoic acid, methyl ester;
SMILES

 

CLASSIFICATION

 

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE

clear liquid

MELTING POINT  
BOILING POINT

100 - 102 C

SPECIFIC GRAVITY 0.87 - 0.875
SOLUBILITY IN WATER Insoluble
pH  
VAPOR DENSITY

 

AUTOIGNITION  

REFRACTIVE INDEX

1.3891
NFPA RATINGS Health: 1; Flammability: 3; Reactivity: 0
FLASH POINT

11 C

STABILITY Stable under normal conditions

GENERAL DESCRIPTION & APPLICATIONS

Pivalic acid is the shortest chain tert-carboxylic acid. Atoms within a molecule occupy space. When atoms are crowded together and overlapped electron clouds, van der Waals repulsions produce an steric hindrance. Steric hindrance may influence conformational equilibria and reactivity. Although steric hindrance is sometimes a unfavorable structure due to less readily reaction, it can provide an escape from undesired side-reactions, can affect varying degrees of rate and energy and can produce the target derivatives which are more resistant to hydrolysis and oxidation than the derivatives from linear chain. Pivalic acid is a key intermediate for the target molecules which require hydrolytic stability and a variety of chemical resistance. Pivalic acid is used mainly in the form of chloride salt (pivaloyl chloride) which are obtained commercially from phosgene. It is used as an intermediate in the production of peroxides and peroxy-esters required for the polymer and agrochemical production. It is used as an intermediate to prepare pharmaceuticals ( Ampicillin, Amoxycillin, Cephalosporins). 2,2-Dimethylbutyric acid is the next shortest chain tert-carboxylic acid which have similar application with pivalic acid.

SALES SPECIFICATION

APPEARANCE

clear liquid

ASSAY

99.0% min

WATER

0.5% max

COLOR, APHA

30 max

TRANSPORTATION
PACKING
170kgs in drum
HAZARD CLASS 3 (Packing Group: I)
UN NO. 1993
OTHER INFORMATION
Hazard Symbols: F, Risk Phrases: 11, Safety Phrases: 9-16-28A-33-37-45